FTIR Spectroscopic Study of the Cl-Atom-Initiated Reactions of Ethylene Oxide in O2/N2 Diluent

J Chen, V Young, PA Hooshiyar, H Niki…

Index: Chen, J.; Young V.; Hooshiyar, P. A.; Niki, H.; Hurley, M. D. Journal of Physical Chemistry, 1995 , vol. 99, # 12 p. 4071 - 4077

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Citation Number: 10

Abstract

(H2C-O-CH2) were studied previously by Bartels et al., using the discharge flow-mass spectrometric method at 298 K in 1 Torr of diluent He.'Interestingly, they reported evidence for the occurrence of both the abstraction and addition channels for the C1+ H2C-O-CH2 reaction with an overall rate constant of 2.8 x lo-" cm3 molecule-'s-'and also for the formation of three isomeric C2H30 radicals (Le., cyclic oxiranyl