Cortical Steroid Analogs. IV. gem-Dialkylacetylcarbinols, Hydroxy Enol Ethers, and Hydroxy Ketals from the Reaction of Grignard Reagents and Ethyl Pyruvate Ketal1a
GW Stacy, IL Klundt, GT Davis, NA Nielsen…
Index: Stacy,G.W. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 1753 - 1757
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Abstract
-Carbon,%---Hydrogen,%-1, R Yield,% Bp, OC Mm nZ6D dz64 Formula Calcd Found Calcd Found d n-CaH95 81 66 4 1.4362 0.9020 CilH2202 70.91 71.04 11.91 11.91 e i-C4H9 45 57-58 0.6 1.4335... CiiHzzOz 70.91 70.89 11.91 11.98 f n-C5Hll 70 141-142 14 1.4392 0.8897 C13H2602 72.84 73.04 12.23 12.34 g i-C5H11 68 67 0.2 1.4335 0.8830 C13H2602 72.84 72.84 12.23 11.96 h nC~ Hi8 82 169-171 14 1.4428 0.8807 C1~ H3002 74.32 ...
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