Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins
MR Gagne, CL Stern, TJ Marks
Index: Gagne, Michel R.; Stern, Charlotte L.; Marks, Tobin J. Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 275 - 294
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Citation Number: 446
Abstract
The use of early transition metal and f-element complexes to effect synthetically useful organic transformations is rapidly becoming an important interfacial boundary between traditional organometallic and synthetic organic chemistry.'A substantial amount of literature has recently emerged concerning stoichiometric activation of, and CC bond formation involving, synthons such as alkynes,* ben~ ynes,~ alkene^,^ imine^,^ and nitrile^.^ A
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