Thermolysis of 4-(ω-hydroxyalkyl)-2, 6-di-tert-butylphenols

AP Krysin, TG Egorova, VG Vasil'ev

Index: Krysin; Egorova; Vasil'Ev Russian Journal of General Chemistry, 2010 , vol. 80, # 2 p. 275 - 283

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Abstract

Abstract The process of thermolysis of tert-butylated hydroxyalkyl phenols includes de-tert- butylation, etherification, and fragmentation of the hydroxyalkyl group. On the basis of the proposed schemes of the mechanism of thermal de-tert-butylation the path of the search for catalysts for the synthesis of 4-hydroxyalkylphenols is defined and transformations of the by- products into biologically active substances were considered.

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