Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1, 2-dienes

E Shirakawa, Y Nakao, T Tsuchimoto…

Index: Shirakawa, Eiji; Nakao, Yoshiaki; Tsuchimoto, Teruhisa; Hiyama, Tamejiro Chemical Communications, 2002 , # 17 p. 1962 - 1963

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Abstract

Polycyclic compounds having linearly-fused six-membered rings can be readily prepared by various modes of cyclization from dienediynes, which were synthesized through the nickel- catalysed alkynylstannylation of 1, 2-dienes followed by the palladium-catalysed oxidative homocoupling of the resulting alkenylstannanes.

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