Russian journal of organic chemistry

Electrochemical fluorination of aromatic compounds in anhydrous HF

BA Shainyan, YS Danilevich

Index: Shainyan; Danilevich Russian Journal of Organic Chemistry, 2006 , vol. 42, # 2 p. 214 - 219

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Citation Number: 2

Abstract

Abstract Electrochemical fluorination of anisole furnished 2-and 4-fluoroanisoles in a 3: 1 ratio, guaiacol, and 4, 4′-dimethoxydiphenyl ether. Phenylacetonitrile alongside the fluorination in the ring suffered the transformation of the cyano group into a trifluoromethyl. 4- Bromobenzamide was fluorinated to a high conversion mostly in the ring to afford predominantly 4-bromo-3, 3, 6, 6-tetrafluoro-1, 4-cyclohexadienecarboxamide. 4- ...

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