Platinum assisted cyclization of S-methyl 3-acyl-2-methyldithiocarbazates under mild conditions. Crystal structure of [Pt2 (µ-SMe)(terpy) 2][ClO4] 3†
…, P Bergamini, V Bertolasi, M Cattabriga…
Index: Annibale, Giuliano; Bergamini, Paola; Bertolasi, Valerio; Cattabriga, Michela; Lazzaro, Antonio; Marchi, Andrea; Vertuani, Gianni Journal of the Chemical Society - Dalton Transactions, 1999 , # 21 p. 3877 - 3882
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Citation Number: 12
Abstract
The reaction of the newly synthesized aqua complex [Pt (terpy)(OH)][BF] with-methyl 3-acyl- 2-methyldithiocarbazates under a variety of experimental conditions has been studied. Using a 2∶ 1 metal to ligand ratio in methanol, a platinum assisted cyclization was observed. The reaction products were Δ-1, 3, 4-oxadiazolin
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