Palladium (0) catalyzed reaction of 1, 3-diene epoxides. A useful method for the site-specific oxygenation of 1, 3-dienes

M Suzuki, Y Oda, R Noyori

Index: Suzuki,M. et al. Journal of the American Chemical Society, 1979 , vol. 101, p. 1623 - 1625

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Citation Number: 127

Abstract

Figure 2. ORTEP diagram of the Ni (ll) complex looking into the “dry cave “. conformation of the ligand (Figures 1 and 2). It clearly forms a hydrophobic cavity or “dry cave” in the vicinity of a vacant metal coordination site. The center of the p-xylyl group is displaced 2.6 A to one side of the nickel and is tilted-23'with respect to the coordination plane (Figure la), thus effectively forming both the roof and back of the cave but leaving a wide opening (-3.6 by ...