(S)-4-tert-Butyl-2-phenyl-2-oxazoline derived palladacycles as efficient catalysts for the decomposition of P= S pesticides

ZL Lu, XS Yang, ZF Guo, RY Wang

Index: Lu, Zhong-Lin; Yang, Xiao-Sheng; Guo, Zhi-Fo; Wang, Rui-Yao Journal of Coordination Chemistry, 2010 , vol. 63, # 14-16 p. 2659 - 2672

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Abstract

Three palladacycles with N, N-trans coordination,(S)-{2-[2-(4-tert-butyl) oxazolinyl] phenyl- C1, N}(4-R-pyridine)(aqua) n palladium (II) triflate (R= CF3, n= 1, 1; R= H, n= 0, 2; R= NMe2, n= 1, 3), have been prepared from the respective chloride precursors and were characterized with IR and 1H-NMR and elemental analyses. The crystal structures of 2 and a pincer complex (S, S)-{2, 6-bis [2-(4-iso-propyl) oxazolinyl] phenyl-N, C1, N} bromo- ...

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