Phosphorus and Sulfur and the Related Elements

NEUE ERGEBNISSE BEI DER SPALTUNG VON THIOETHERN MIT NATRIUM IN FLÜSSIGEM AMMONIAK. ABTRENNUNG VON 1.3. 5-TRITHIAPENTAN UBER 1.5- …

E Weissflog

Index: Weissflog, Eckhard Phosphorus and Sulfur and the Related Elements, 1983 , vol. 14, p. 233 - 240

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Abstract

Abstract Recent results show that the cleavage of oligomeric and polymeric thioformaldehydes or polymethylene-disulfide by sodium in liquid ammonia, followed by treatment with an excess of hydrochloric acid, leads to the formation of mercaptothioethers, CH3 (SCH2) nSH, bis-mercaptothioethers, HS (CH2S) mH and thioalkanes, CH3 (SCH2) xSCH3. The identification and isolation of various components of these mixtures are ...