The preparation of several permethylated linear polysilanes. From octasilane to dodecasilane
M Kumada, M Ishikawa, S Maeda
Index: Kumada,M. et al. Journal of Organometallic Chemistry, 1966 , vol. 5, p. 120 - 123
Full Text: HTML
Citation Number: 4
Abstract
Abstract Five new permethylated linear polysilanes of the formula CH 3 [Si (CH 3) 2] n CH 3, where n is equal to 8, 9, 10, 11 and 12, have been prepared from the co-condensation of appropriate chlorosilanes using sodium-potassium alloy as condensing agent in a benzene- ligroin or benzene-n-heptane mixture. These compounds are all white crystalline substances. The melting points display a regular progression as the number of silicon ...
Related Articles:
Photoinduced electron-transfer reaction of 7, 8-disilabicyclo [2.2. 2] octa-2, 5-dienes
[Kako; Hatakenaka; Kakuma; Ninomiya; Nakadaira; Yasui; Iwasaki; Wakasa; Hayashi Tetrahedron Letters, 1999 , vol. 40, # 6 p. 1133 - 1136]
Photoinduced electron-transfer reaction of 7, 8-disilabicyclo [2.2. 2] octa-2, 5-dienes
[Kako; Hatakenaka; Kakuma; Ninomiya; Nakadaira; Yasui; Iwasaki; Wakasa; Hayashi Tetrahedron Letters, 1999 , vol. 40, # 6 p. 1133 - 1136]