Indirect electrochemical oxidation of cyclic ketones: Influence of ring size, mediator and supporting electrolyte on the result of the reaction
F Barba, MN Elinson, J Escudero, SK Feducovich
Index: Barba, Fructuoso; Elinson, Michail N.; Escudero, Jose; Feducovich, Sergey K. Tetrahedron, 1997 , vol. 53, # 12 p. 4427 - 4436
Full Text: HTML
Citation Number: 14
Abstract
The result of the indirect electrochemical oxidation of cyclic ketones in methanol in an undivided cell in the presence of sodium halides depends on the ring size of ketone and the type of mediator. Selectivity of the reaction in some cases and current efficiency are increased by addition of supporting electrolyte-sodium hydroxide. Formation of cyclic 2, 2- dimethoxycycloalkanols and the electrochemically induced Favorskii rearrangement with ...
Related Articles:
[Surmont, Riccardo; Verniest, Guido; De Groot, Alex; Thuring, Jan Willem; De Kimpe, Norbert Advanced Synthesis and Catalysis, 2010 , vol. 352, # 16 p. 2751 - 2756]
Arynic condensation of ketone enolates. 16. Efficient access to a new series of benzocyclobutenols
[Carre, Marie-Christiane; Gregoire, Brigitte; Caubere, Paul Journal of Organic Chemistry, 1984 , vol. 49, # 11 p. 2050 - 2052]