New synthetic routes to gem-dinitroalkanes and derivatives
CD Bedford, AT Nielsen
Index: Bedford,C.D.; Nielsen,A.T. Journal of Organic Chemistry, 1978 , vol. 43, # 12 p. 2460 - 2463
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Citation Number: 19
Abstract
gem-Dinitroalkanes (3) have been prepared by reaction of nitro olefins with organolithium reagents, followed by treatment with tetranitromethane. 2-Alkoxy-gem-dinitroalkanes (2) are obtained similarly by employing alkoxides as the basic addend. The preparation of 1-bromo derivatives of 2 and their reaction with bases are described. The 1H and I3C NMR spectra of 2 and 3 are presented and discussed.
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