Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
…, G Ji, G Wu, M Li, Y Zhang, J Wang
Index: Wang, Xi; Zhou, Yujing; Ji, Guojing; Wu, Guojiao; Li, Ming; Zhang, Yan; Wang, Jianbo European Journal of Organic Chemistry, 2014 , vol. 2014, # 15 p. 3093 - 3096
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Citation Number: 20
Abstract
Abstract A strategy to introduce the SCF 3 group through the Cu I-promoted reaction of diazo compounds with the nucleophilic AgSCF 3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C (sp 3)–SCF 3 bond. Mechanistically, migratory insertion of SCF 3-bearing Cu carbene intermediates is involved in this transformation.
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