The Reactions of Some Triarylsilanes with Methyllithium and Phenylisopropylpotassium
RA Benkeser, FJ Riel
Index: Benkeser; Riel Journal of the American Chemical Society, 1951 , vol. 73, p. 3472
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Citation Number: 23
Abstract
In all cases the corresponding triarylmethylsilane was formed. The reaction of tri-p- chlorophenylsiane, tris-(p-tritluoromethylpheny1)-silane, tri-p-tolylsilane and tri-p- anisylsilane,~ 1 Ith methyllithium was investigated. Tri-o-tolylsilane reacts with phenylisopropylpotassium in a manner similar to tri-o-tolylmethane in that all three methyl groups are metalated. When the metalated product is carbonated, a silane tricarboxylic ...
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