HeI and HeII photoelectron spectroscopic investigation of subsituent effects in aminosilanes

A Nagy, JC Green, L Szepes, L Zanathy

Index: Nagy, Attila; Green, Jennifer C.; Szepes, Laszlo; Zanathy, Laszlo Journal of Organometallic Chemistry, 1991 , vol. 419, # 1 p. 27 - 42

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Citation Number: 2

Abstract

Abstract The HeI and HeII ultraviolet photoelectron spectra of PhΦNH, PhNHSiMe 3, PhΦNSiMe 3,(PhΦN) 2 SiMe 2, Ph 2 NSiMe 2 Φ, Ph 2 NSiPH 3 and Ph 2 NSiΦ 3 (Me= CH 3; Ph= C 6 H 5; Φ= C 6 F 5) are reported. Tentative assignment is given for the low-IE (ionization energy) region. HeI and HeII relative band intensities have been obtained from these spectra and also from the spectra of PhBr, ΦBr, PhNH 2 ΦNH 2, Ph 2 NH and Ph 2 ...