Synthese und BECKMANN??Umlagerung von 1??Acetyl??bicyclo [2.2. 2] octan??oxim. Bicyclo [2.2. 2] octan??Reihe, 8. Mitteilung
HJ Fischer, CA Grob
Index: Fischer,H.P.; Grob,C.A. Helvetica Chimica Acta, 1964 , vol. 47, # 2 p. 564 - 567
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Citation Number: 16
Abstract
Abstract The synthesis of 1-acetyl-bicyclo [2.2. 2] octane oxime is described. The p-toluene- sulfonic ester of this compound affords l-acetamido-bicyclo [2.2. 2] octane (7) upon B ECKMANN rearrangement, and therefore possesses the anti-R/OTs configuration 6. 1- Acetamido-bicyclo [2.2. 2] octane (7) is also obtained by the H OFMANN reaction of l- carbamoyl-bicyclo [2.2. 2] octane (3).
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