A Quantitative Structure–Reactivity Assessment of Phenols by Investigation of Rapid Iodination Kinetics Using Hydrodynamic Voltammetry: Applicability of the …

VT Borkar, SL Bonde, VT Dangat

Index: Borkar, Vitthal T.; Bonde, Shantaram L.; Dangat, Vijay T. International Journal of Chemical Kinetics, 2013 , vol. 45, # 11 p. 693 - 702

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Citation Number: 9

Abstract

ABSTRACT Halogenations of aromatic substrates in aqueous medium are essentially electrophilic substitutions proceeding at rates concomitant with the nature of the substrates and substituent motifs. Kinetics as an investigatory tool for the quantitative assessment of the structure–reactivity correlation in these reactions for a diverse range of substrates has rarely been reported, presumably due to the rapidity of these reactions in aqueous medium. We ...