New method for Hofmann rearrangement
S Jew, HG Park, HJ Park, M Park, Y Cho
Index: Jew, Sang-sup; Park, Hyeung Geun; Park, Hee-Joo; Park, Min-soo; Cho, Youn-sang Tetrahedron Letters, 1990 , vol. 31, # 11 p. 1559 - 1562
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Citation Number: 32
Abstract
Treatment of a series of primary aliphatic and aromatic carboxamides ( - ) with NBS-Hg(OAc) 2 -R'OH (A), dibromantin-Hg(OAc) 2 -R'OH (B), NBS-AgOAc-R'OH (C), or dibromantin-AgOAc-R'OH (D) in DMF under argon provides corresponding carbamates ( - ) in nearly quantitative yields. ... Treatment of a series of carboxamides with A, B, C, or D in DMF provides the corresponding carbamates in nearly quantitative yields.
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