Spiro-λ 4-sulfanes with O-ligands of different electronegativity in axial positions. A comparison of CH 2 O–S IV–OCO and CH 2 O–S+ IV··· O [double bond, length as m- …

D Szabó, I Kapovits, G Argay, M Czugler…

Index: Szabo, Denes; Kapovits, Istvan; Argay, Gyula; Czugler, Matyas; Kalman, Alajos; Koritsanszky, Tibor Journal of the Chemical Society. Perkin Transactions 2, 1997 , # 5 p. 1045 - 1053

Full Text: HTML

Citation Number: 0

Abstract

Two novel diaryl (alkoxy)(acyloxy) spiro-λ4-sulfanes (3 and 5) exhibiting isomerism in relation to swapping of the five-and six-membered spiro-rings and two analogous cyclic alkoxysulfonium salts (4 and 6) with intramolecular S··· O interaction have been prepared and their molecular structures determined by X-ray diffraction. In all cases the arrangement of the ligands about the central sulfur atom shows a slightly distorted trigonal bipyramidal ( ...