The Journal of Organic Chemistry

LFER correlation of 13C chemical shift in para-substituted phenyl isocyanide: implications for formation of a unique polymer

M Kim, WB Euler, W Rosen

Index: Kim, Misoo; Euler, William B.; Rosen, William Journal of Organic Chemistry, 1997 , vol. 62, # 11 p. 3766 - 3769

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Citation Number: 10

Abstract

The phrase “linear free energy relationship”(LFER) as applied in organic chemistry to the Hammett equation grew out of the seminal studies of Hammett. 1 Normally such an LFER refers to a linear correlation where a chemical or spectroscopic process is used as a probe. The resultant equilibrium, rate constants, or excitation energies for the processes are then correlated in the presence of a variety of perturbations. As a consequence, substituent ...