Novel nonenzymic heterolysis of an allyl phosphate ester by organoaluminum reagents

Y Kitagawa, S Hashimoto, S Iemura…

Index: Kitagawa,Y. et al. Journal of the American Chemical Society, 1976 , vol. 98, p. 5030 - 5031

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Citation Number: 52

Abstract

Although nonenzymic polyolefin terminal epoxide cyclizations are among the most fascinating biogenetic-like terpenoid syntheses and have received an immense amount of study,'another important counterpart of terpene biosynthesis, an allyl phosphate ester cyclization, has never been developed to a useful level due to the lack of a satisfactory reagent to promote the controlling heterolysis of these esters2 We now report the ...

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