The Journal of organic chemistry

New generation of organosilyl radicals by photochemically induced homolytic cleavage of silicon-boron bonds

A Matsumoto, Y Ito

Index: Biffar, Werner; Noeth, Heinrich; Schwerthoeffer, Ruediger Liebigs Annalen der Chemie, 1981 , # 11 p. 2067 - 2080

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Citation Number: 29

Abstract

... 11 Of note is, however, that sterically bulky substituents on either silicon or boron atoms remarkably affected UV absorption of bis(dialkylamino)organosilylboranes. ... The 11 B chemical shifts of 1a,b appeared in downfield compared to those of 1c−e (Table 1). 13 ...

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