Organic mass spectrometry

A mass spectral rearrangement of 2??(alkylamino) benzoic acid derivatives and related heterocyclic systems

RJ Barbuch, NP Peet

Index: Barbuch, Robert J.; Peet, Norton P. Organic Mass Spectrometry, 1988 , vol. 23, p. 816 - 820

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Abstract

Abstract The behavior of a series of 2-(alkylamino) benzoic acid derivatives and related heterocylic systems has been investigated using electron impact mass spectrometry and fragmentation pathways have been formulated. Deuterium-labeled and 13 C-labeled compounds were used in this study. An interesting rearrangement of the alkylamino compounds, in which the alkyl substituent is incorporated into a fulvene ion, was observed ...