Tetrahedron letters

Laser flash photolysis study of the reactivity of α-ketenylbenzocyclobutenone with water and alcohols

NC de Lucas, J Andraos, JC Netto-Ferreira…

Index: De Lucas, Nanci Camara; Andraos, John; Netto-Ferreira; Scaiano Tetrahedron Letters, 1995 , vol. 36, # 5 p. 677 - 680

Full Text: HTML

Citation Number: 9

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Photolysis of 2-diazo-1,3-indandione leads to ketene formation via the Wolff rearrangement. Ketene 2 hydrates to produce enol 3a that rearranges to 4a. Homophthalic acid 5a is formed by photodecomposition of 4a upon prolonged irradiation. ... Photolysis of 2-diazo-1,3- ...

Related Articles:

Pyrolytic and photochemical Wolff rearrangement of diazoindanones. Synthesis of 2-carboalkoxybenzocyclobutenones

[Spangler,R.-J. et al. Journal of Organic Chemistry, 1977 , vol. 42, p. 1697 - 1703]

More Articles...