Tetrahedron

Enzymatic desymmetrization of prochiral 2-benzyl-1, 3-propanediol derivatives: A practical chemoenzymatic synthesis of novel phosphorylated tyrosine analogues

T Yokomatsu, T Minowa, T Murano, S Shibuya

Index: Yokomatsu, Tsutomu; Minowa, Takayuki; Murano, Tetsuo; Shibuya, Shiroshi Tetrahedron, 1998 , vol. 54, # 32 p. 9341 - 9356

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Citation Number: 33

Abstract

(Phosphonomethyl) phenylalanine (Pmp) and (phosphonodifluoromethyl) phenylalanine (F2Pmp) as well as their β-amino acid congeners were prepared as a protecting variant amenable to the peptide synthesis from readily available 2-benzyl-1, 3-propandiols possessing either a diethylphosphonomethyl-or diethylphosphonodifluoromethyl functionality at the para-position via the lipase-catalyzed desymmetrization.

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