Russian journal of general chemistry

(chloromethyl) phosphoryl compounds in the arbuzov reaction

AN Yarkevich, EN Tsvetkov

Index: Yarkevich; Tsvetkov Russian Journal of General Chemistry, 2002 , vol. 72, # 3 p. 486 - 487

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Citation Number: 8

Abstract

phosphite it undergoes intramolecular cyclization leading to diphospholane VI. In this case, the high temperature of the process and removal of butyl chloride from the reaction sphere favor cyclization. Similar formation of stable five-membered rings,(1, 2-oxaphospholanes) was previously observed on attempted preparation of (3-halopropyl) phosphonates [3, 4] and also while using them as alkylating agents in polar media [4].