The Journal of Physical Chemistry

Infrared spectra of diacetylene-hydrogen fluoride complexes in solid argon

KO Patten Jr, L Andrews

Index: Patten, Kenneth O.; Andrews, Lester Journal of Physical Chemistry, 1986 , vol. 90, # 17 p. 3910 - 3916

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Citation Number: 19

Abstract

Diacetylene-hydrogen fluoride complexes and their deuterated counterparts have been characterized in solid argon at 10 K by infrared spectroscopy. The observation of two new sets of HF stretching, CH stretching, and CH bending absorptions indicates that two primary product 1: l complexes were trapped in the matrix. These absorption bands characterize a C4H2--HF? r complex and a C4H2--FH u complex whose relative yields exhibit a ...

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