Allylic Chlorides. XVIII. Preparation and Properties of 1, 1, 3-Trichloro-2-fluoro-1-propene and 1, 1, 2, 3-Tetrachloro-1-propene1

LF Hatch, DW McDonald

Index: Hatch; McDonald Journal of the American Chemical Society, 1952 , vol. 74, p. 3328

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Citation Number: 7

Abstract

The 1, 1, 3-trichloro-2-fluoro-1-propene was synthesized from l, l-dichloro-2-fluoro-l-propene by the use of N-bromosuccinimide followed by hydrolysis of the S-bromo-l, l-dichloro-2- fluoro-l-propene to 3, 3-dichloro-2-fluoro-2-propen-l-ol and conversion of this allylic alcohol to the desired allylic chloride in a manner similar to that previously used to prepare the 1, 3- dichloro-2-fluoropropenes from the 1-chloro-Zfluoro-1-propenes.'The 1, 1, 2, 3-tetrachloro- ...