Chemistry of tetrahedral intermediates. 11. Stereochemical studies on hemiorthothiol and hemiorthothiolate tetrahedral intermediates
FF Khouri, MK Kaloustian
Index: Khouri, Farid F.; Kaloustian, Moses K. Journal of the American Chemical Society, 1986 , vol. 108, # 21 p. 6683 - 6695
Full Text: HTML
Citation Number: 15
Abstract
Abstract: This study deals with hemi~ rthothiol-RC (OR')~ SH-tetrahedral intermediates including (a) two acyclic ones of type [Ill,(b) two types of monocyclics [12] and [13], and (c) four bicyclic systems [14],[MI,[16], and [17]. The breakdown of [ll](R= Ph, R'= Et) led to thiono esters 34 and 35; that of [12](R= Me, Ph) resulted in hydroxy thiono esters 36-39, whereas the cleavage of [I31 (R= Me, Et) yielded thionolactones 49-53 and hydroxy thiono esters ...
Related Articles:
[Krawczyk, Andrzej R.; Jones, J. Bryan Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1795 - 1801]
Cyclopropylcarbinyl radicals in the photochemistry of. beta.,. gamma.-cyclopropyl ketones
[Takakis,J.M.; Agosta,W.C. Journal of the American Chemical Society, 1979 , vol. 101, # 9 p. 2383 - 2389]
[Wenkert, Ernest; Davis, Linda L.; Mylari, Banavara L.; Solomon, Mary F.; Silva, Roberto R. da; et al. Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3242 - 3247]
[Wenkert, Ernest; Davis, Linda L.; Mylari, Banavara L.; Solomon, Mary F.; Silva, Roberto R. da; et al. Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3242 - 3247]
[Tudor; Vogel Journal of the Chemical Society, 1934 , p. 1250,1252]