Efficient and stereoselective synthesis of allylic ethers and alcohols
J Pospíšil, IE Markó
Index: Pospisil, Jiri; Marko, Istvan E. Organic Letters, 2006 , vol. 8, # 26 p. 5983 - 5986
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Citation Number: 30
Abstract
A short and efficient synthesis of allylic TBS ethers and allylic alcohols has been developed, based upon a unique Kocienski-Julia olefination reaction. Allylic alcohols and allylic ethers are obtained in good to excellent yields and with high (E)-selectivity. The conditions are mild and the procedure is broadly applicable.
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[Sakaguchi, Kazuhiko; Yamamoto, Masahiro; Kawamoto, Tetsuo; Yamada, Takeshi; Shinada, Tetsuro; Shimamoto, Keiko; Ohfune, Yasufumi Tetrahedron Letters, 2004 , vol. 45, # 30 p. 5869 - 5872]