Polyaminophosphine containing dendrimers. Syntheses and characterization

…, D Prevote, AM Caminade, JP Majoral

Index: Galliot, Christophe; Prevote, Delphine; Caminade, Anne-Marie; Majoral, Jean-Pierre Journal of the American Chemical Society, 1995 , vol. 117, # 20 p. 5470 - 5476

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Citation Number: 78

Abstract

Abstract: The synthesis of phosphorus containing dendrimers 2-[Go]-2-[G3] and 3-[Go]-3- [G1] is achieved from the hexapodant N~ P~(OC~ H&HO)~~-[GO] used as a core. It involves iterative reaction sequences: condensation reaction of GO] with methylhydrazine followed by treatment of the resulting hydrazone with either chlorodiphenylphosphine or chlorodiazaphospholane, the last step being the reaction of the dendrimer possessing ...