Nitrogen atom transfer to alkenes utilizing Chloramine-T as a nitrogen source
T Ando, S Minakata, I Ryu, M Komatsu
Index: Ando, Takeya; Minakata, Satoshi; Ryu, Ilhyong; Komatsu, Mitsuo Tetrahedron Letters, 1998 , vol. 39, # 3-4 p. 309 - 312
Full Text: HTML
Citation Number: 125
Abstract
Aziridination of alkenes proceeds successfully using Chloramine-T (N-chloro-N-sodio-p- toluenesulfonamide). When anhydrous Chloramine-T was added to an acetonitrile solution of alkenes in the presence of various CuCl catalysts and MS-5A, the corresponding aziridines were obtained in moderate to good yields.
Related Articles:
Recent advances in the stereoselective synthesis of aziridines
[Li, Yang; He, Jiayue; Khankhoje, Vineeta; Herdtweck, Eberhardt; Koehler, Klaus; Storcheva, Oksana; Cokoja, Mirza; Kuehn, Fritz E. Dalton Transactions, 2011 , vol. 40, # 21 p. 5746 - 5754]
[Verma, Sanny; Jain, Suman L. RSC Advances, 2013 , vol. 3, # 43 p. 19830 - 19833]
[Au, Sze-Man; Huang, Jie-Sheng; Yu, Wing-Yiu; Fung, Wai-Hong; Che, Chi-Ming Journal of the American Chemical Society, 1999 , vol. 121, # 39 p. 9120 - 9132]