Arenediazonium salts: New probes of the interfacial compositions of association colloids. 1. Basic approach, methods, and illustrative applications

A Chaudhuri, JA Loughlin, LS Romsted…

Index: Chaudhuri, Arabinda; Loughlin, John A.; Romsted, Laurence S.; Yao, Jihu Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8351 - 8361

Full Text: HTML

Citation Number: 93

Abstract

Abstract: Product yields from the reactions of two different arenediazonium salts, z-ArN2+ BF4-, bound to cetyltrimethylammonium halide ((CTA) X; X= C1, Br) micelles and to aqueous three-component (CTA) X microemulsions containing an alcohol (R'OH), either 1-butanol (BuOH) or 1-hexanol (HexOH), are “snapshots” of the relativequantities of halide ion, water, and alcohol nucleophiles at the aggregates' interfaces. Yields of aryl ether, aryl halide, ...