Tetrahedron letters

Stereoselective synthesis of di-and trisubstituted alkenes via intermolecular addition of vinyl radicals to alkenes

K Miura, D Itoh, T Hondo, A Hosomi

Index: Miura, Katsukiyo; Itoh, Daisuke; Hondo, Takeshi; Hosomi, Akira Tetrahedron Letters, 1994 , vol. 35, # 51 p. 9605 - 9608

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Citation Number: 9

Abstract

Abstract Vinyl radicals, generated from the reaction of vinyl iodides with tributylstannyl radical, react with electron-deficient alkenes to give di-or trisubstituted alkenes in moderate to good yields. The stereoselectivity is largely dependent on the substituent at 1-and 2- position of vinyl iodides.

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