Transacylation of α-Aryl-β-keto Esters

…, M Tamura, K Hori, Y Tohda, M Ariga

Index: Nishiwaki, Nagatoshi; Tanaka, Chitose; Asahara, Motoki; Asaka, Noriko; Tohda, Yasuo; Ariga, Masahiro Heterocycles, 1999 , vol. 51, # 3 p. 567 - 574

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Citation Number: 20

Abstract

The acyl group of an α-aryl-β-keto ester was readily transferred to N-, O-, and S- nucleophiles. The transacylation from arylated diethyl 3-oxoglutarate to amines led to unsymmetrical malonic acid amide esters in high yields. The present reaction proceeded