A novel method for converting ketones to. alpha.-diketones. The reaction of enamino ketones with singlet oxygen
HH Wasserman, JL Ives
Index: Wasserman,H.H.; Ives,J.L. Journal of the American Chemical Society, 1976 , vol. 98, p. 7868 - 7869
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Citation Number: 47
Abstract
The oxidation of a methylene group a to a ketone to form an a-diketone is an important functional group transformation which has many applications in organic synthesk2 Conventional reagents for accomplishing this transformation, including selenium dioxide3a or alkyl nitrites in acid or base, 3b often lead to further oxidation or side reactions because of the strong reaction conditions employed. Other methods involving a-halogenation or a- ...
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