A new protocol for the formation of carbamates and thiocarbamates using carbamoyl imidazolium salts

RA Batey, C Yoshina-Ishii, SD Taylor, V Santhakumar

Index: Batey, Robert A.; Yoshina-Ishii, Chiaki; Taylor, Scott D.; Santhakumar Tetrahedron Letters, 1999 , vol. 40, # 14 p. 2669 - 2672

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Citation Number: 37

Abstract

Carbamoyl imidazolium salts are demonstrated to act as useful carbamoylation reagents, in reactions with alcohols, phenols, thiols and thiophenols to form carbamates and thiocarbamates under relatively mild conditions. The salts are stable and easily prepared from the corresponding amines using CDI.