Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes

M Lurdes S áCristiano, AW Robert

Index: Cristiano, M. Lurdes S.; Johnstone, Robert A. W.; Price, Peter J. Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 12 p. 1453 - 1459

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Citation Number: 29

Abstract

Transfer hydrogenolysis of 5-allyloxy-l-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C– O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending on the catalyst used.