Organometallics

Metal-free hydrogen activation by the frustrated Lewis pairs of ClB (C6F5) 2 and HB (C6F5) 2 and bulky Lewis bases

C Jiang, O Blacque, H Berke

Index: Biscoe, Mark R.; Uyeda, Christopher; Breslow, Ronald Organic Letters, 2004 , vol. 6, # 23 p. 4331 - 4334

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Citation Number: 63

Abstract

... Volume: Page ... stoichiometric mixtures of 2,2,6,6-tetramethylpiperidine (TMP) or of the sterically hindered phosphines R 3 P (R = t-Bu ... chloride/hydride metathesis also produces the known equilibrium mixture of the monomeric and dimeric borohydride [HB(C 6 F 5 ...