Potassium tert??Butoxide??Catalyzed Dehydrogenative Si O Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
A Weickgenannt, M Oestreich
Index: Weickgenannt, Andreas; Oestreich, Martin Chemistry - An Asian Journal, 2009 , vol. 4, # 3 p. 406 - 410
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Citation Number: 20
Abstract
Abstract As simple as it gets! Potassium tert-butoxide alone catalyzes the direct dehydrogenative Si [BOND] O coupling of several synthetically important silanes with 1, 2, and even 3 alcohols without the need for stoichiometric hydrochloric acid scavengers. The stereoretentive mechanism is probed with a silicon-stereogenic silane.
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