Preparation and spectral properties of symmetrical S-aryl arenesulfonothioates (thiosulfonates)
F Freeman, LG Bartosik, NV Bui…
Index: Freeman, Fillmore; Bartosik, Lisa G.; Bui, Nghe Van; Keindl, Monica C.; Nelson, Eric L. Phosphorus and Sulfur and the Related Elements, 1988 , vol. 35, p. 375 - 386
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Abstract
Abstract Arenesulfinyl chlorides (4-XC6H4S (O) Cl);×= H, CH3, F, Cl, Br) react with activated zerovalent zinc in benzene at 6 to 8° C to give symmetrical S-aryl arenesulfonothioates (thiosulfonates) in good to excellent yields. 2-and 3-Substituted arenesulfinyl chlorides (X= Cl, CH3) give a mixture of products (disulfide, thiosulfinate, and/or thiosulfonate). 2, 4, 6- Triisopropylbenzenesulfinyl chloride reacts with zinc in 1, 2-dimethoxyethane to give S-(2, ...
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