Hydroboration. 57. Hydroboration with 9-borabicyclo [3.3. 1] nonane of alkenes containing representative functional groups
HC Brown, J Chen
Index: Brown, Herbert C.; Chen, Jackson C. Journal of Organic Chemistry, 1981 , vol. 46, # 20 p. 3978 - 3988
Full Text: HTML
Citation Number: 96
Abstract
The hydroboration of alkenes containing representative functional groups was examined with 9-borabicyclo [3.3. l] nonane (9-BBN) in order to extend the hydroboration reaction for the preparation of functionally substituted organoboranes. Terminal alkenes containing a remote functional group are hydroborated with a remarkable regioselectivity (298% terminal), producing the corresponding stable organoboranes. 9-BBN hydroborates the ...
Related Articles:
[Alnajjar, Mikhail S.; Kuivila, Henry G. Journal of Organic Chemistry, 1981 , vol. 46, # 6 p. 1053 - 1057]
[Adam, Waldemar; Zang, Gerald Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3315 - 3323]
185??nm??Photochemie von Olefinen, gespannten Kohlenwasserstoffen und Azoalkanen in Lösung
[Adam, Waldemar; Oppenlaender, Thomas Angewandte Chemie, 1986 , vol. 98, # 8 p. 659 - 670]
Carbenes and the oxygen-hydrogen bond: bicycloalkylidenes
[Kirmse, Wolfgang; Meinert, Thomas; Modarelli, David A.; Platz, Matthew S. Journal of the American Chemical Society, 1993 , vol. 115, # 20 p. 8918 - 8927]
The Relative Stability of Bridged Hydrocarbons. Norbornene and Nortricyclene1
[Schleyer Journal of the American Chemical Society, 1958 , vol. 80, p. 1700,1701, 1703]