An effective strategy for acyclic synthesis via iterative rearrangement of allylic glycolates. Synthesis of a pine sawfly pheromone
J Kallmerten, M Balestra
Index: Kallmerten, James; Balestra, Michael Journal of Organic Chemistry, 1986 , vol. 51, # 14 p. 2855 - 2857
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Citation Number: 23
Abstract
Summary: The stereocontrolled preparation of extended acyclic systems using the iterative enolate Claisen rear- rangement of allylic glycolates is described. This strategy has been demonstrated in the stereospecific synthesis of a pine sawfly pheromone. ... Sir: The development of stereoselective techniques for use in the linear elaboration of complex acyclic targets has been a focus of considerable attention in recent years.'+ While linear construction of extended acyclic systems offers ...
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[Gould, Thomas J.; Balestra, Michael; Wittman, Mark D.; Gary, Jill A.; Rossano, Lucius T.; Kallmerten, James Journal of Organic Chemistry, 1987 , vol. 52, # 17 p. 3889 - 3901]