Palladium??Catalyzed Intramolecular C–O Bond Formation: An Approach to the Synthesis of Chiral Benzodioxocines

…, TP Majhi, B Achari, P Chattopadhyay

Index: Neogi, Arpita; Majhi, Tirtha P.; Achari, Basudeb; Chattopadhyay, Partha European Journal of Organic Chemistry, 2008 , # 2 p. 330 - 336

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Citation Number: 11

Abstract

Abstract Palladium-catalyzed intramolecular aryl etherification using bulky binaphthylphosphane or bis (diphenylphosphanyl) ferrocene ligands is shown to be a convenient method for the synthesis of eight-membered oxygen heterocycles. Application of this methodology to a sugar derivative led to the synthesis of chiral benzodioxocine.(© Wiley- VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)