Convenient n-formylation of amines in dimethylformamide with methyl benzoate under microwave irradiation
D Yang, HB Jeon
Index: Yang, Dongsik; Jeon, Heung Bae Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 5 p. 1424 - 1426
Full Text: HTML
Citation Number: 14
Abstract
Formylation of amines is a very useful process in synthetic organic chemistry. Formamides are a class of important intermediates that have been widely used in synthesis of pharmaceutically important compounds. 1 In addition, formamides have been also extensively employed in organic synthesis as protecting group of amines, 2 precursor for formamidines3 and isocyanide4 preparation, an intermediate for mono methylated amines ...
Related Articles:
Microwave assisted amine formylation by a heterogeneous HCO2H/SiO2 system
[Khoramabadi-zad, Ahmad; Veisi, Hojat; Akbari, Safar-Ali; Shiri, Azam Journal of the Chinese Chemical Society, 2007 , vol. 54, # 2 p. 479 - 481]
[Mihara, Masatoshi; Ishino, Yoshio; Minakata, Satoshi; Komatsu, Mitsuo Synthesis, 2003 , # 15 p. 2317 - 2320]
[Mihara, Masatoshi; Ishino, Yoshio; Minakata, Satoshi; Komatsu, Mitsuo Synthesis, 2003 , # 15 p. 2317 - 2320]
Thermal and microwave-assisted N-formylation using solid-supported reagents
[Desai, Bimbisar; Danks, Timothy N.; Wagner, Gabriele Tetrahedron Letters, 2005 , vol. 46, # 6 p. 955 - 957]