Cross-hetero-dehydrogenative coupling reaction of phosphites: a catalytic metal-free phosphorylation of amines and alcohols
J Dhineshkumar, KR Prabhu
Index: Dhineshkumar, Jayaraman; Prabhu, Kandikere Ramaiah Organic Letters, 2013 , vol. 15, # 23 p. 6062 - 6065
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Citation Number: 29
Abstract
Phosphorylation of amines, alcohols, and sulfoximines are accomplished using molecular iodine as a catalyst and H2O2 as the sole oxidant under mild reaction conditions. This method provides an easy route for synthesizing a variety of phosphoramidates, phosphorus triesters and sulfoximine-derived phosphoramidates which are of biological importance.
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