Studies on Pd/NiFe2O4 catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls

SR Borhade, SB Waghmode

Index: Borhade, Sanjay R.; Waghmode, Suresh B. Beilstein Journal of Organic Chemistry, 2011 , vol. 7, p. 310 - 319

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Citation Number: 35

Abstract

Abstract Palladium supported on nickel ferrite (Pd/NiF 2 O 4) was found to be a highly active catalyst for the Suzuki coupling reaction between various aryl halides and arylboronic acids. The reaction gave excellent yields (70–98%) under ligand free conditions in a 1: 1 DMF/H 2 O solvent mixture, in short reaction times (10–60 min). The catalyst could be recovered easily by applying an external magnetic field. The polyaryls were similarly synthesized.

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