Catalytic Diastereo??and Enantioselective Annulations between Transient Nitrosoalkenes and Indoles

…, D Stephens, G Hernandez, R Mendoza…

Index: Zhang, Yu; Stephens, David; Hernandez, Graciela; Mendoza, Rosalinda; Larionov, Oleg V. Chemistry - A European Journal, 2012 , vol. 18, # 52 p. 16612 - 16615

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Citation Number: 25

Abstract

Asymmetric reactions of nitroso compounds offer unique advantages for the formation of CÀO and CÀN bonds especially in the area of biomedically relevant heterocycles.[1] Heretofore, however, diastereo-and enantioselective transformations of nitroso compounds have been limited to stoichiometric chiral auxiliary-controlled processes.[2] Several recent examples of catalytic enantioselective transformations of nitrosoarenes have ...