Catalyst dependent mechanistic paths in the reactions of ethyl diazoacetate with β-keto esters
AC Lottes, JA Landgrebe, K Larsen
Index: Lottes, Andrew C.; Landgrebe, John A.; Larsen, Kristin Tetrahedron Letters, 1989 , vol. 30, # 31 p. 4093 - 4096
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Citation Number: 9
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The catalyzed decomposition of ethyl diazoacetate in the presence of β-keto esters produces regioisomeric enol ethers and the diester from formal carbenoid insertion into the α-CH bond. The product distribution is very catalyst dependent. ... Equilibration does occur in ...
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